This application note demonstrates that Mini-Z Sulfur Analyzer can meet the requirements of ASTM D Sulfur Testing ASTM D Video. Intertek Sulfur Testing for Fuels, Crude Oil and Hydrocarbons. Learn more about Intertek’s Deer Park laboratory, located in. The repeatability measurements of sulfur as per ASTM D test are presented in Figure 2. The repeatability measurements of diesel road fuel sample with.
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Please login to read this s2622 or create an account. For many years, professionals in the petroleum industry have faced challenges regarding compliance and quality of product.
Ultra-low sulfur (ULS) in petroleum fuels by ASTM D2622-10
These challenges are made more difficult by the variety of regulations and specifications, and the implications they present for their refining process. Regulators across the globe are moving to even more restrictive aetm on sulfur asm in a variety of fuels with many countries now requiring maximum sulfur concentration in automotive fuels of 10 to 15 parts per million ppm.
These regulations have furthered the need for refineries to maximize the precision of their sulfur analysis methodology. Desulfurization processes are expensive utilizing catalyst, hydrogen, and heat.
By using a more precise sulfur measurement technique, refiners can produce product closer to the specification maximums, reducing giveaway and saving money. This savings is illustrated in Figure 1. In addition to production efficiencies, refiners can avoid inaccurate reporting which can lead to regulatory missteps and contract disputes by using a test method with better precision.
With several different methodology options for sulfur analysis available, refineries, terminals, and test inspection certification companies must take care to select a method that produces the least amount of variability in their measurements. Each participating laboratory performs analyses following ASTM methods for various test parameters, including sulfur, using the samples provided.
D, D, and D First, an understanding of the test methods is critical to interpreting the data presented. Rather than aztm filters or traditional crystals that are flat or singly curved, MWDXRF incorporates doubly curved crystal DCC optics to provide a focused, monochromatic excitation X-ray beam to excite the sample.
A second DCC optic is used to collect the sulfur signal and focus it onto the detector. Upon exposure, fluorescent X-rays are emitted from the sample at energy levels that are unique to each element.
Fuel Property Testing: Sulfur
Additionally, the background signal, an energy region not characteristic of sulfur or other interfering elements, is collected and subtracted from the sulfur signal to improve precision and LOD. To isolate the sulfur signal and to reduce noise, WDXRF utilizes a filter and a collection crystal before the sulfur signal reaches the detector.
The sample is combusted in the tube, and sulfur is oxidized to sulfur dioxide SO 2 in the oxygen-rich atmosphere. Water produced during the sample combustion is removed by a membrane dryer and the sample combustion gasses are exposed to ultraviolet UV light. The resulting signal is a measure of the sulfur contained in the sample.
The data shown represents sulfur data collected throughout the study from January to December Understanding the Data Mean Concentration and Reproducibility Both graphs and tables shown below track asrm sample concentration and reproducibility R. Reproducibility is the difference between two single and independent results obtained by asstm operators applying the same test method in different laboratories using different apparatus on identical test material.
A lower reproducibility value correlates to a better level of precision which can minimize risks from inaccurate d262 such as regulatory fines and contract disputes.
The data presented is filtered to show all samples whose average concentration ranged between 5 and 15 ppm. These values were chosen based on the most common regulatory requirements for sulfur content in automotive fuel in Europe, United States, China, and others around the world.
It is critical for an analyzer to have low reproducibility values better precision when measuring these aetm of samples. When interpreting the data, keep in mind: The average R value across the 3 years of study data is the key performance indicator shown in both graphs and tables. In both Tables 1 and 2, test method D contains most of the lower R values marked as green which indicates better PTP precision.
When measuring for critical elements such as sulfur, a highly precise testing method is vital. Low precision methods can lead to products being off spec which can costs refineries millions of dollars in fines, or product downgrading.
Reducing variability in sulfur analysis is critical to reducing sulfur giveaway, and from the data shown, MWDXRF methods offer the highest level of precision and reliability.
Sulfur in Automotive Fuels with Mini-Z Sulfur (ASTM D) – | Rigaku
Whether monitoring ULSD or considering the refinery process strategy, refiners should take care when selecting the methodology for elemental analysis. This method does not rely on combustion for analysis. With easy to operate instruments, MWDXRF analyzers provide refineries, terminals, and test inspection certification companies with an efficient, reliable, and highly accurate way to determine the sulfur and chlorine content of their products.
Samples are measured directly, which means it can analyze even the heaviest of hydrocarbons like crude e2622 or coker residuals, without the hassle of boats, injectors, asgm, or changing detectors.
With no compromises in detection, performance and reliability, Sindie is the ideal sulfur analytical solution from ultra-low sulfur diesel and gasoline to heavy fuel oil and crudes. Sindie G3 delivers excellent precision with an LOD of 0. This instrument uses Accucells for hassle-free sample preparation. Atmospheric distillation unit offers perfection from Make your daily measuring routine a piece of cake: Spectro Scientific acquired by Ametek Dec 14 Dd2622 Characterisation of Hydrocarbons in Shale R New, robust and user-friendly general purpose monitor Dec 17 Read Safe satm reliable pressure calibration and pressure New FM approved liquid analyser system is safe for h Miniature spectrometer spearheads development of a n How To Specify a Spectrometer.
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